Packing of inhibitor molecules during area-selective atomic layer deposition studied using random sequential adsorption simulations
نویسندگان
چکیده
Area-selective atomic layer deposition (ALD) is of interest for applications in self-aligned processing nanoelectronics. Selective generally enabled by functionalization the area where no growth desired with inhibitor molecules. The packing these molecules, terms molecule arrangement and surface density, plays a vital role deactivating blocking precursor adsorption. In this work, we performed random sequential adsorption (RSA) simulations to investigate small inhibitors (SMIs) on order predict how effective SMI blocks These provide insight into molecules depends size, shape, their ability diffuse over surface. Based RSA simulations, statistical method was developed analyzing sizes gaps between adsorbed serving as quantitative parameter effectiveness blocking. This validated experimental studies using several alcohol SMIs an area-selective process SiO 2 . It demonstrated that insightful straightforward screening potential ALD.
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ژورنال
عنوان ژورنال: Journal of vacuum science & technology
سال: 2022
ISSN: ['2327-9877', '0734-211X']
DOI: https://doi.org/10.1116/6.0002096